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VACUUM ›› 2020, Vol. 57 ›› Issue (2): 27-32.doi: 10.13385/j.cnki.vacuum.2020.02.06

• Thin Film • Previous Articles     Next Articles

Study on Tribological Properties of (Ti, Cr) N Films

ZHONG Li, SHEN Li-ru, CHEN Mei-yan, LIU Tong, DAN Min, JIN Fan-ya   

  1. Southwestern Institute of Physics, Chengdu 610207, China
  • Received:2019-02-15 Online:2020-03-25 Published:2020-04-24

Abstract: In order to study the relationship between composition of composite film and target used in multi-arc ion plating technology, and to compare the tribological properties of (Ti, Cr) N film with different composition, five targets - namely pure Ti target, pure Cr target and titanium-chromium alloy targets with titanium-chromium ratio of 9:1, 4:1 and 1:1 were designed and fabricated. Scanning electron microscopy was used to observe the micro-morphology of the film. X-ray energy spectrum analyzer was used to analyze the composition of the micro-area qualitatively and semi-quantitatively. X-ray diffraction was used to analyze the structure of the film. The wear resistance of the film was tested by friction and wear tests. Finally, the wear volume was calculated with the width, depth and length of the wear marks, and the wear volume was used to characterize the wear resistance of different films. The results show that composition of film prepared by the alloy target is not the same as that of the target, but all of them show TiCrN(200)preferred orientation. The surface of TiCrN film prepared by pure target is the most delicate and the roughness of TiCrN film decreases with the increase of Cr content. The hardness and wear resistance of TiCrN films are obviously better than those of pure target films. Ti0.3Cr0.23N films prepared by target(Ti:Cr=4:1)have the highest hardness(HV0.053274.9)and the best wear resistance. When the film is prepared by alloy target, the composition of the film is greatly affected by the ionization rate of single metal, not the metal ratio of the target. And adding hard elements to the film can improve the quality and wear resistance of the film.

Key words: multi-arc ion plating technology, alloy target, TiCrN film, wear resistance

CLC Number: 

  • TG144
[1] 李玉海,张勤,刘馨,等, TC4钛合金微弧氧化复合陶瓷膜制备及耐磨性能研究[J]. 功能材料, 2015, 46(9):9128-9132.
[2] 张弛. 偏压、靶电流对多弧离子镀制备TiN/TiAlN复合膜组织形貌及性能的影响[D]. 沈阳:沈阳大学, 2013.
[3] Bobzin K, Lugscheider E, Maes M.PVD-Low temperature deposition process for machine parts for integration of tri-biological functions within the surface[J]. Material wissenschaft und werkstofftechnik, 2004, 35(10-11):843-850.
[4] Ueda M, Silva M M, Lepienski C M, et al.High Temperature Plasma Immersion Ion Implantation of Ti6Al4V[J]. Surface and coatings technology. 2007,201: 4953-4956.
[5] Berger M, Wiklund U, Eriksson M, et al.The multilayer effect in abrasion-optimising the combination o hard and tough phase[J]. Surface and coatings technology, 1999,195:99-110.
[6] 赵旭红, 李志强, 徐佰明,等, 2011. R26合金制螺栓盐浴渗铬防咬死性能研究[C]//中国动力工程学会. 第九届电站金属材料学术年会论文集(第二卷). 成都: 中国动力工程学会学术委员会: 182-188.
[7] Philippon D, Godinho V, Nagy P M, et al.Endurance of Ti-Al-Si-N coatings: Effect of Si and bias on wear and adhesion[J]. Wear, 2015, 270(7): 541-549.
[8] Glatz S A, Koller C M, Bolvardi H, et al.Influence of Mo on the structure and the tribomechanical properties of arc evaporated Ti-Al-N[J]. Surface and coatings technology, 2017, 311:330-336.
[9] 高亚丽. AZ91HP镁合金激光表面改性研究[D]. 大连: 大连理工大学, 2006.
[10] 金犁. 多弧离子镀制备Ti(1-x)AlxN薄膜的工艺及其性能研究[D]. 武汉: 武汉科技大学, 2006.
[11] 孔德军, 付贵忠, 王文昌,等. 阴极弧离子镀制备AlCrN涂层的高温摩擦磨损行为[J]. 真空科学与技术学报, 2014, 34(7):700-706.
[12] 汤旭东, 王小峰, 龙振湖. 减少阴极弧金属等离子体源液滴的技术措施[J]. 机械工程师, 2003(6):39-41.
[13] 董中林,多弧离子镀大颗粒的去除及脉冲偏压对膜层特性的影响研究[D]. 安徽:合肥工业大学,2017.
[14] Lee J W, Tien S K, Kuo Y C.The effects of pulse frequency and substrate bias the mechanical properties of CrN coatings deposited by pulsed DC magnetron sputtering[J]. Thin solid films, 2006, 494(3): 161-167.
[15] 蔡志海, 张平, 底月兰,等. Ti含量对(Cr,Ti)N复合膜组织结构与性能的影响[J]. 装甲兵工程学院学报, 2010, 24(3):76-80.
[16] 刘正林编著,摩擦学原理[M], 北京: 高等教育出版社,2009.
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