真空 ›› 2024, Vol. 61 ›› Issue (5): 64-73.doi: 10.13385/j.cnki.vacuum.2024.05.09
刘燕文1, 尚新文1, 陆玉新2, 田宏1, 赵恒邦1
LIU Yan-wen1, SHANG Xin-wen1, LU Yu-xin2, TIAN Hong1, ZHAO Heng-bang1
摘要: 为了满足高频率、小型化微波真空电子器件需求,寻找合适的阴极和激光系统,研究了一种新型锑铯光电阴极的制备方法。发射材料的蒸发源采用多孔钨海绵扩散阻挡层代替镍管加热技术,以控制发射材料的蒸发速率。为了增强阴极的吸附能力,提高光的吸收率,通过纳米粒子薄膜和离子轰击技术对阴极基体表面进行了改性处理,研究了改性前后阴极表面结构、成分及其光电发射特性。结果表明:表面改性对阴极的量子效率具有很大的提升作用,分析认为阴极表面积的增大是发射性能提高的主要原因,光吸收率的增大也提高了阴极的量子效率。
中图分类号: TN105.1
[1] LIU Y W, TIAN H, LU Y X, et al.Influences of diamond material on heat dissipation capabilities of helical slow wave structures[J]. IEEE Transactions on Electron Devices, 2019, 66(12): 5321-5326. [2] 刘燕文, 田宏, 韩勇, 等. 支取发射电流过程对热阴极温度影响的研究[J]. 中国科学E辑: 技术科学, 2008, 38(9): 1515-1520. [3] LIU Y W, TIAN H, HAN Y, et al.Temperature variation of a thermionic cathode during electron emission[J]. Science in China Series E: Technological Sciences, 2008, 51: 1497-1501. [4] 王小霞, 廖显恒, 罗积润, 等. 新型贮存式氧化物阴极寿命机理的初步探讨[J]. 物理学报, 2009, 58(2): 1280-1286. [5] WANG X X, LIAO X H, LUO J R.Study on the Ni-Re-Ir sponge oxide cathode[J]. IEEE Transactions on Electron Devices, 2012, 59(2): 492-495. [6] GÄRTNER G, JANIEL P, RAASCH D. Direct determination of electrical conductivity of oxide cathodes[J]. Applied Surface Science, 2002, 201(1-4): 35-40. [7] RAJU R S, MALONEY C E.Characterization of an impregnated scandate cathode using a semiconductor model[J]. IEEE Transactions on Electron Devices, 1994, 41(12): 2460-2467. [8] WANG J S, LIU W, LI L L, et al.A study of scandia-doped pressed cathodes[J]. IEEE Transactions on Electron Devices, 2009, 56(5): 799-804. [9] MELNIKOVA I P, VOROZHEIKIN V G, USANOV D A.Correlation of emission capability and longevity of dispenser cathodes with characteristics of tungsten powders[J]. Applied Surface Science, 2003, 215(1-4): 59-64. [10] LIU Y W, TIAN H, HAN Y, et al.Study on the emission properties of the impregnated cathode with nanoparticle films[J]. IEEE Transactions on Electron Devices, 2012, 59(12): 3618-3624. [11] 刘燕文, 刘胜英, 田宏, 等. 用于空间行波管的高效率覆膜阴极组件的研究[J]. 真空科学与技术学报, 2006, 26(3): 240-242. [12] BARIK R K, BERA A, RAJU R S, et al.Development of alloy-film coated dispenser cathode for terahertz vacuum electron devices application[J]. Applied Surface Science, 2013, 276: 817-822. [13] ISAGAWA S, HIGUCHI T, KOBAYASHI K, et al.Application of M-type cathodes to high-power cw klystrons[J]. Applied Surface Science, 1999, 146(1-4): 89-96. [14] 刘燕文, 田宏. 小多注速调管覆膜阴极的制备方法: CN00132779.8[P].2002-06-19. [15] ZHU J, WANG S L, XIE S H, et al.Hexagonal single crystal growth of WO3 nanorods along a [110] axis with enhanced adsorption capacity[J]. Chemical Communications, 2011, 47(15): 4403-4405. [16] WANG H L, HAO Q L, YANG X J, et al.A nanostructured graphene/polyaniline hybrid material for supercapacitors[J]. Nanoscale, 2010, 2(10): 2164-2170. [17] WANG S L, HE Y H, LIU X L, et al.Large-scale synthesis of tungsten single-crystal microtubes via vapor-deposition process[J]. Journal of Crystal Growth, 2011, 316(1): 137-144. [18] WHALEY D, DUGGAL R, ARMSTRONG C, et al.High average power field emitter cathode and testbed for X/Ku-band cold cathode TWT[C]// 2013 IEEE 14th International Vacuum Electronics Conference (IVEC). Paris, France: IEEE, 2013. [19] LIU Y W, ZHANG G M, XUE Z Q, et al.The high field enhancement of photoemission from Na2KSb photocathodes[J]. Nuclear Instruments and Methods in Physics Research Section A, 1996, 376(1): 146-147. [20] 刘燕文, 王国建, 田宏, 等. 激光驱动的新型光电阴极[J]. 中国科学: 信息科学, 2021, 51(9): 1575-1586. [21] 刘燕文, 田宏, 陆玉新, 等. 用于微波真空电子器件的光电阴极[J]. 真空, 2019, 56(6): 7-11. [22] 刘燕文, 张耿民, 刘惟敏, 等. 激光驱动的钠钾锑光电阴极的稳定性研究[J]. 中国激光, 1996, 23(3): 255-259. [23] LEE C H, OETTINGER P E, PUGH E R, et al.Electron emission of over 200 A/cm2 from a pulsed-laser irradiaied photocaihode[J]. IEEE Transactions on Nuclear Science, 1985, 32(5): 3045-3047. [24] STEIN W, WARREN R, WINSTON J, et al.The accelerator for the Los Alamos free-electron laser-IV[J]. IEEE Journal of Quantum Electronics, 1985, 21(7): 889-894. [25] OETTINGER P E, SHEFER R E, BIRX D L, et al.Photoelectron sources: selection and analysis[J]. Nuclear Instruments and Methods in Physics Research Section A, 1988, 272(1/2): 264-267. [26] 张篁, 陈德彪, 江孝国, 等. 直线感应加速器用光阴极实验研究[J]. 强激光与粒子束, 2010, 22(3): 583-586. [27] 刘燕文, 张耿民, 刘惟敏, 等. 激光驱动的钠钾锑光电阴极的光电发射特性[J]. 北京大学学报: 自然科学版, 1996, 32(1): 96-102. [28] SOMMER A H.Brief history of photoemissive materials[C]//Photodetectors and Power Meters. San Diego, CA, United States: SPIE, 1993, 2022: 2-17. [29] SOMMER A H.光电发射材料:制备、特性与应用 [M]. 侯洵, 译. 北京:科学出版社, 1979:1-4. [30] WU C I, KAHN A.Negative electron affinity and electron emission at cesiated GaN and AlN surfaces[J]. Applied Surface Science, 2000, 162: 250-255. [31] 乔建良, 常本康, 钱芸生, 等. 负电子亲和势GaN光电阴极光谱响应特性研究[J]. 物理学报, 2010 (5): 3577-3582. [32] ULMER M P, WESSELS B W, SHAHEDIPOUR F, et al.Progress in the fabrication of GaN photocathodes[C]// Photodetectors: Materials and Devices VI. San Jose, CA, United States: SPIE, 2001, 4288: 246-253. [33] BATES R, CAMPBELL M, DA VIA C, et al.Developments in GaAs pixel detectors for X-ray imaging[C]// 1997 IEEE Nuclear Science Symposium Conference Record. NM, USA:IEEE, 1997: 534-540. [34] MACHUCA F, LIU Z, SUN Y, et al.Oxygen species in Cs/O activated gallium nitride (GaN) negative electron affinity photocathodes[J]. Journal of Vacuum Science & Technology B, 2003, 21(4): 1863-1869. [35] 刘燕文, 田宏, 李芬, 等. 碱金属源的制备装置及制备方法: CN202110202475.9[P].2021-06-22. [36] 刘燕文, 田宏, 李芬, 等. 光电阴极及其制备方法: CN201810512769.X[P].2018-08-31. [37] 刘燕文, 李芬, 田宏, 等. 一种光电阴极及其制备方法: CN202011316694.1[P].2021-02-26. [38] 刘燕文, 田宏, 李芬, 等. 钨海绵基体浸铜方法及装置: CN202111095729.8[P].2021-12-14. [39] 刘燕文, 陆玉新, 张晓林, 等. 多孔钨材料及零件的研究进展[J]. 真空, 2023, 60(2): 1-13. [40] 刘燕文, 王小霞, 朱虹, 等. 钨海绵基体去铜的方法: CN201310208189.9 [P].2014-03-12. [41] 刘燕文, 田宏, 陆玉新, 等. 用于浸渍阴极的钨海绵基体的净化[J]. 真空科学与技术学报, 2018, 38(2): 144-149. [42] ALIVISATOS A P.Semiconductor clusters, nanocrystals, and quantum dots[J]. Science, 1996, 271(5251): 933-937. [43] VOSSMEYER T, KATSIKAS L, GIERSIG M, et al.CdS nanoclusters: synthesis, characterization, size dependent oscillator strength, temperature shift of the excitonic transition energy, and reversible absorbance shift[J]. The Journal of Physical Chemistry, 1994, 98(31): 7665-7673. [44] 王国建, 刘燕文, 李芬, 等. 离子束表面处理对光电阴极发射的影响[J]. 物理学报, 2021, 70(21): 356-363. [45] CURREN A N, LONG K J, JENSEN K A, et al.An effective secondary electron emission suppression treatment for copper MDC electrodes[C]//Proceedings of IEEE International Electron Devices Meeting. Washington, DC, USA: IEEE, 1993: 777-780. [46] DING M Q, HUANG M G, FENG J J, et al.Ion surface modification for space TWT multistage depressed collectors[J]. Applied Surface Science, 2008, 255(5): 2196-2199. [47] 刘燕文, 田宏, 朱虹, 等. 电子轰击材料出气性能[J]. 真空科学与技术学报, 2017, 37(4): 363-368. [48] 崔云康, 张晓兵, 雷威, 等. 电真空器件残气质谱分析和贮存寿命的快速测试研究[J]. 真空科学与技术学报, 2007, 27(1): 80-83. [49] 刘燕文, 孟宪展, 田宏, 等. 空间行波管极高真空的获得与测量[J]. 真空, 2018, 55(5): 25-28. [50] 郎兴凯, 贾鹏, 陈泳屹, 等. 窄线宽半导体激光器研究进展[J]. 中国科学: 信息科学, 2019, 49(6): 649-662. [51] LIU Y, TIAN H, LI F, et al.Effects of nanomaterials on Cs3Sb photocathode emission performance[J]. AIP Advances, 2022, 12(3): 035004. [52] LIU Y, LI F, TIAN H, et al.Influence of ion beam surface treatment on the emission performance of photocathodes[J]. Nanoscale Advances, 2022, 4(17): 3517-3523. |
[1] | 刘燕文, 陆玉新, 张晓林, 孟鸣凤, 李芬, 赵恒邦, 王小霞. 多孔钨材料及零件的研究进展*[J]. 真空, 2023, 60(2): 1-13. |
[2] | 石文奇, 张连正, 陆玉新, 田宏, 朱虹, 赵恒邦, 王小霞, 刘燕文. 光电阴极的研究进展*[J]. 真空, 2020, 57(3): 42-48. |
[3] | 刘燕文, 田宏, 陆玉新, 石文奇, 朱虹, 李芬, 李云, 谷兵, 王小霞. 用于微波真空电子器件的光电阴极*[J]. 真空, 2019, 56(6): 7-11. |
|