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真空 ›› 2020, Vol. 57 ›› Issue (3): 34-36.doi: 10.13385/j.cnki.vacuum.2020.03.08

• 薄膜 • 上一篇    下一篇

氮化碳薄膜的光电特性研究*

沈洪雪1, 李刚1, 姚婷婷1, 金葆琪2, 金克武1, 王天齐1   

  1. 1.浮法玻璃新技术国家重点实验室,安徽 蚌埠 233018;
    2.安徽财经大学,安徽 蚌埠 233018
  • 收稿日期:2019-06-17 发布日期:2020-06-18
  • 通讯作者: 李刚,博士,高级工程师。
  • 作者简介:沈洪雪(1981-),男,安徽省淮南市人,硕士,高级工程师。
  • 基金资助:
    安徽省重点研究和开发计划项目(1804a09020061),安徽省科技重大专项(17030901085)

Study on the Photoelectric Properties of N Doped CN Thin Films

SHEN Hong-xue1, LI Gang1, YAO Ting-ting1, JIN Bao-qi2, JIN Ke-wu1, WANG Tian-qi1   

  1. 1. State Key Laboratory for Advanced Technology of Float Glass, Bengbu 233018, China;
    2. AnHui University of Finance & Economics, Bengbu 233018, China
  • Received:2019-06-17 Published:2020-06-18

摘要: 以高纯石墨为靶材,Ar、N2为溅射和反应气体,采用直流磁控溅射法,制备了一系列不同N掺杂量的氮化碳薄膜。利用XRD、SEM、分光光度计、高阻抗率计等检测手段对薄膜的成分、形貌、透过率、电阻率等进行表征。结果表明:CN薄膜已初具晶型;随着溅射腔室中N2含量的增加,薄膜中N含量先增加后减少最后趋于稳定状态,薄膜的电阻率维持在(10-5~1015)Ω·cm范围内变动;透过率基本维持在85%~91%之间。N的掺入对薄膜中的sp3杂化C起到了稳定的作用。

关键词: sp3杂化, 透过率, 电阻率, 晶型

Abstract: Using high purity graphite as target, Ar and N2 as sputtering and reacting gases, a series of CN thin films with different N content were prepared by DC magnetron sputtering. The composition, morphology, transmittance and electrical resistivity of the films were detected by means of XRD, SEM, spectrophotometer and high impedance meter. The results show that the CN film has the first crystal shape, and with the increase of N2 content in the sputtering chamber, the content of N in the film increases first and then decreases finally to the stable state. The resistivity of the film is maintained within the range of 10-5Ω·cm to 1015Ω.cm and the transmittance is basically maintained between 85% and 91%. The incorporation of N played a stabilizing role in the sp3 hybrid C in the films.

Key words: sp3 hybrids, transmittance, resistivity, crystal type

中图分类号: 

  • TQ174
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