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真空 ›› 2023, Vol. 60 ›› Issue (1): 13-16.doi: 10.13385/j.cnki.vacuum.2023.01.02

• 薄膜 • 上一篇    下一篇

固态全无机电致变色玻璃窗透过率与遮蔽系数测试与分析*

酆纲1,2, 孟政1,2,3, 杨学东4, 张浩运4, 余刚1,3, 高辉1, 王伟才1, 宋猛1, 孙勇1,3, 孔壮1,3, 贾金升1, 汪洪1,3   

  1. 1.中国建筑材料科学研究总院有限公司 绿色建筑材料国家重点实验室,北京 100024;
    2.中建材科创新技术研究院（山东）有限公司 山东省无机功能材料与智能制造重点实验室,山东 枣庄 277100;
    3.太阳能与建筑节能玻璃材料加工技术北京市重点实验室,北京 100024;
    4.中国国检测试控股集团股份有限公司,北京100024
  • 收稿日期:2021-12-29 出版日期:2023-01-25 发布日期:2023-02-07
  • 通讯作者: 孟政,博士,高级工程师。
  • 作者简介:酆纲（1972-）,男,北京市人,工程师。
  • 基金资助:
    *国家重点研发计划课题：固态全无机电致/热致变色镀膜玻璃制造技术与产业化示范（NOs.2016YFB0303901）

Measurement and Analysis of Light Transmittance and Shielding Coefficient of All Inorganic Solid-state Electrochromic Window

FENG Gang1,2, MENG Zheng1,2,3, YANG Xue-dong4, ZHANG Hao-yun4, YU Gang1,3, GAO Hui1, WANG Wei-cai1, SONG Meng1, SUN Yong1,3, KONG Zhuang1,3, JIA Jin-sheng1, WANG Hong1,3   

  1. 1. State Key Laboratory of Green Building Materials, China Building Materials Academy, Beijing 100024, China;
    2. Shandong Key Laboratory of Inorganic Functional Materials and Intelligent Manufacturing, CNBM Technology Innovation Academy, Zaozhuang 277100, China;
    3. Beijing Key Laboratory of Solar Energy and Building Energy-saving Glass Materials Processing Technology, Beijing 100024, China;
    4. China Building Material Test & Certification Group, Beijing 100024, China
  • Received:2021-12-29 Online:2023-01-25 Published:2023-02-07

摘要： 为了更好地发挥电致变色玻璃主动调控光谱的属性,为电致变色玻璃在建筑上的应用提供理论指导,以两玻一腔中空玻璃为例讨论了可见光透过率和遮蔽系数（节能效果）变化。研究发现,获得更大的可见光透过率差（褪色态-着色态）重点是要提高电致变色玻璃透过率,但相比于成本更高的电致变色玻璃,提高Low-E玻璃透过率更为现实。为了更大限度地发挥电致变色玻璃的节能特性,分别将电致变色玻璃放置于中空玻璃的室内侧与室外侧测试,结果表明当电致变色玻璃位于室外侧时,遮蔽系数变化幅度最大（0.46）,更能适应多种场景下的使用,但同时也对电致变色玻璃的膜层性能提出了更高的要求。

关键词: 电致变色玻璃, 褪色态, 着色态, 可见光透过率, 遮蔽系数, 中空玻璃, Low-E玻璃

Abstract: In order to make better use of the properties of active spectrum control of electrochromic glass and provide theoretical support for the application of electrochromic glass in architecture, the sealed insulating glass unit was taken as an example to discuss the changes of visible light transmittance and shielding coefficient(energy saving effect). It is found that in order to obtain a larger visible light transmittance difference(bleach state minus color state), the key point is to improve the transmittance of electrochromic glass. However, compared with the electrochromic glass with higher cost, it is more realistic to improve the transmittance of Low-E glass.In order to give full play to the energy-saving characteristics of electrochromic glass, the electrochromic glass was placed on the outdoor side and indoor side of insulating glass respectively for testing. The results show that when the electrochromic glass is located on the outdoor side, the change of shielding coefficient is the largest(0.46), which is more suitable for a variety of scenarios. At the same time, the better performance of electrochromic glass film is required.

Key words: electrochromic glass, bleach state, color state, visible light transmittance, shielding coefficient, insulating glass, Low-E glass

中图分类号: 

  • TQ171
[1] O′BRIEN N A, GORDON J, MATHEW H, et al. Electrochromic coatings-applications and manufacturing issues[J]. Thin Solid Films, 1999, 345(2): 312-318.
[2] LEE E S, DIBARTOLOMEO D.Application issues for large-area electrochromic windows in commercial buildings[J]. Solar Energy Materials and Solar Cells, 2002, 71(4): 465-491.
[3] 林改. 全固态电致变色智能窗[J]. 玻璃, 2015, 42(3): 3-7.
[4] 殷顺湖, 徐键, 洪樟连. 灵巧窗电致变色复合薄膜材料、器件及应用[J]. 材料导报, 1995, 70(5): 69-70.
[5] 王晓光, 江月山, 杨乃恒, 等. 固态电致变色薄膜器件的发展现状[J]. 真空, 1996(4): 6-12.
[6] GRANQVIST C G.Handbook of inorganic electrochromic materials[M]. Elsevier, 1995: 6-15.
[7] 张翔, 李文杰, 李垚, 等. 无机全固态电致变色器件研究进展[J]. 材料科学与工艺, 2020, 28(3): 140-149.
[8] 代强, 刘静, 汪洪. 反应磁控溅射氧化钨电致变色薄膜结构与性能[J]. 硅酸盐学报, 2018, 46(7): 978-986.
[9] 孟政, 刘静, 汪洪. 固态全无机电致变色器件透过光谱计算与测试[J]. 真空科学与技术学报, 2018, 38(7): 633-635.
[10] HUANG Q, DONG G, XIAO Y, et al.Electrochemical studies of silicon nitride electron blocking layer for all-solid-state inorganic electrochromic device[J]. Electrochimica Acta, 2017, 252: 331-337.
[11] LIU Q, DONG G, CHEN Q, et al.Charge-transfer kinetics and cyclic properties of inorganic all-solid-state electrochromic device with remarkably improved optical memory[J]. Solar Energy Materials and Solar Cells, 2018, 174: 545-553.
[12] LIU Q, CHEN Q, ZHANG Q, et al.Dynamic behaviors of inorganic all-solid-state electrochromic device: Role of potential[J]. Electrochimica Acta, 2018, 269: 617-623.
[13] DONG D, WANG W, ALINE R, et al.Life-cycling and uncovering cation-trapping evidence of a monolithic inorganic electrochromic device: Glass/ITO/WO3/LiTaO3/ NiO/ITO[J]. Nanoscale, 2018, 10(35): 16521-16530.
[14] DONG D, WANG W, ALINE R, et al.Lithium trapping as a degradation mechanism of the electrochromic properties of all-solid-state WO3//NiO devices[J]. Journal of Materials Chemistry C, 2018, 6: 9875-9889.
[15] WANG S C, LIU K Y, HUANG J L.Tantalum oxide film prepared by reactive magnetron sputtering deposition for all-solid-state electrochromic device[J]. Thin Solid Films, 2011, 520(5): 1454-1459.
[16] 夏翥杰, 张治国, 王红莉, 等. WO3薄膜制备及其电致变色性能研究[J]. 真空, 2020, 57(2): 47-52.
[17] 魏梦瑶, 王辉, 韩文芳, 等. 中频磁控溅射制备氧化钨薄膜及电致变色性能研究[J]. 真空, 2021, 58(5): 50-56.
[18] 代强, 刘静, 孟政, 等. 钛掺杂氧化钨薄膜结构与电致变色性能研究[J]. 真空, 2018, 55(2): 14-18.
[19] DONG D M, WANG W W, BARNABÉ A, et al.Enhanced electrochromism in short wavelengths for NiO:(Li, Mg)films in full inorganic device ITO/NiO:(Li, Mg)/ Ta2O5/WO3/ITO[J]. Electrochimica Acta, 2018, 263: 277-285.
[20] 全国建筑用玻璃标准化技术委员会. 建筑玻璃可见光透射比, 太阳光直接透射比, 太阳能总透射比, 紫外线透射比及有关窗玻璃参数的测定: GB/T 2680-2021[S]. 北京: 中国标准出版社, 2021: 130-131.
[1] 陈海峰, 林乐忠. Low-E玻璃镀膜线C1室设计[J]. 真空, 2019, 56(5): 47-51.
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