欢迎访问沈阳真空杂志社 Email Alert    RSS服务

VACUUM ›› 2021, Vol. 58 ›› Issue (2): 15-19.doi: 10.13385/j.cnki.vacuum.2021.02.04

• Thin Film • Previous Articles     Next Articles

Effect of Evaporation Rate on the Properties of ZnS Films

LI Kun, XIONG Yu-qing, WANG Hu, ZHANG Kai-feng, WANG Lan-xi, ZHOU Hui   

  1. Science and Technology on Vacuum Technology and Physics Laboratory, Lanzhou Institute of Physics, Lanzhou 730000, China
  • Received:2020-03-24 Online:2021-03-25 Published:2021-04-09

Abstract: This work aims to study the effects of evaporation rate on refractive index, surface morphology and stress of ZnS films. Electron beam evaporation was used to prepare the ZnS films. Firstly, the film was deposited on K9 substrate and the transmittance curve was tested by spectrophotometer. The refractive index of the film was obtained by spectral inversion method and the surface morphology of the sample was characterized by atomic force microscope. The film was also deposited on PI substrate and the stress of the film was calculated by Stoney formula. With the increase of evaporation rate, the refractive index first increases and then decreases. At the wavelength of 2000 nm, the maximum refractive index was 2.21, and the minimum was 2.07. The higher the evaporation rate, the looser the surface structure of the film sample is. The films prepared at different evaporation rates all show compressive stress. Increasing the evaporation rate can significantly reduce the stress of films. The performance of ZnS film was significantly affected by the evaporation rate. When the rate was 1.5 nm/s, the refractive index can reach the maximum value. When the rate was 2.5 nm/s, the stress can obtain the minimum value.

Key words: evaporation rate, ZnS, film, refractive index, stress

CLC Number: 

  • O484.4
[1] DONG Q, XIAN W G.Design and characterization of one-dimensional photonic crystals based on ZnS/Ge for Infrared-visible compatible stealth applications[J]. Optical Materials, 2016, 62: 52-56.
[2] AHMADVAND H, MOGHADAM Z.Design and fabrication of multi-layers infrared antireflection coating consisting of ZnS and Ge on ZnS substrate[J]. Infrared Physics & Technology, 2016, 75: 18-21.
[3] 陈焘, 罗崇泰, 王多书, 等. 离子束辅助沉积和真空退火对硫化锌薄膜应力的影响[J]. 真空科学与技术学报, 2009, 29(z1): 55-58.
[4] 于天燕, 朱福荣, 刘定权, 等. 硫化锌透镜中长波红外宽带增透膜的研制[J]. 光学学报, 2005, 25(2): 270-273.
[5] FAN X, ZHANG M L.ZnS/ZnO heterojunction nanoribbons[J]Advanced Materials, 2009, 21(23): 2393-2396.
[6] 宋凌云, 蔡春锋, 刘博智, 等. ZnS薄膜参数对有机/无机复合发光器件特性的影响[J]. 光谱学与光谱分析, 2014, 34(4): 888-901.
[7] 赵培, 刘定权, 徐晓峰, 等. 溅射条件对ZnS薄膜的光学常量和微结构的影响[J]. 光子学报, 2008, 37(12): 2483-2485.
[8] 孙常鸿, 张鹏, 张天宁, 等. 硫化锌薄膜的原子层沉积生长及表征[J]. 红外, 2017, 38(2): 1-6.
[9] 张蕾, 方龙, 刘攀克, 等. PLD法在c面蓝宝石衬底上制备纤锌矿ZnS外延薄膜[J]. 功能材料, 2016, 47(5): 05224-05226.
[10] 石刚, 李亚军, 左少华, 等. 原位退火对磁控溅射制备的ZnS薄膜微结构和发光性能的影响[J]. 红外与毫米波学报, 2011, 30(6): 507-510.
[11] 刘颖, 缪彦美, 郝瑞亭, 等. 化学浴沉积法制备ZnS薄膜的结构及可见-近红外光谱特性研究[J]. 人工晶体学报, 2015, 44(3): 610-615.
[12] 唐晋发, 顾培夫, 刘旭, 等. 现代光学薄膜技术[M]. 杭州: 浙江大学出版社, 2007: 68-70.
[13] 李凯朋, 王多书, 李晨, 等. 光学薄膜参数测量方法研究[J]. 红外与激光工程, 2015, 44(3): 1048-1052.
[14] 王多书, 李佑路, 李凯朋, 等. 红外光学薄膜材料折射率温度特性的研究方法[J]. 红外与激光工程, 2018, 47(4): 040061-040065.
[15] 虞益挺, 苑伟政, 乔大勇. 曲率测量技术在微机电系统薄膜残余应力测量中的应用[J]. 机械工程学报, 2007, 43(3): 78-81.
[16] WANG H J, DENG H A, CHIANG S Y, et al.Development of a process modeling for residual stress assessment of multilayer thin film structure[J]. Thin Solid Films, 2015, 584: 146-153.
[1] ZHANG Yu-chen, ZHANG Hai-bao, CHEN Qiang. Review on Semi-Conductive ZnO Thin Film Prepared by HiPIMS [J]. VACUUM, 2021, 58(1): 72-77.
[2] LIU Lu-sheng, ZHAI Zhao-feng, YANG Bing, SONG Hao-zhe, YU Qi, SHI Dan, YUAN Zi-yao, LU Zhi-gang, CHEN Bin, ZHOU Mei-qi, LI Hai-ning, YU Biao, HUANG Nan, JIANG Xin. Development of Hot Filament Chemical Vapor Deposition Equipment for Continuous Diamond Film Preparation [J]. VACUUM, 2020, 57(6): 1-4.
[3] FENG Shen-shen, WANG Liang, LI Bin, YU Qing-zhou, GAN Shu-yi. Research Progress of Corrosion-Resistant and Conductive Films on Stainless Steel Substrate Prepared by Magnetron Sputtering [J]. VACUUM, 2020, 57(6): 11-17.
[4] GUO Zhi-shuai, FEI Shu-guo, YIN Xiao-jun, GAO Peng, ZHAO Shuai-feng, WANG Yin-he, SONG Guang-hui. Design and Coating Technology of Optical Filter for Infrared Thermometry Imaging [J]. VACUUM, 2020, 57(6): 18-22.
[5] DAI Yong-xi, YANG Qian-qian, DENG Jin-xiang, KONG le, LIU Hong-mei, YANG Kai-hua, WANG Ji-you. Preparation and Study of ZTO Thin Film Doped with Different Si Content [J]. VACUUM, 2020, 57(6): 23-26.
[6] WEI Xian-lu, GONG Chen-yang, XIAO Jian-rong. Structure and Optical Properties of MoS2 Thin Films Prepared by RF Reactive Magnetron Sputtering [J]. VACUUM, 2020, 57(5): 11-13.
[7] ZHOU Gang, LV Kai, LIU Yuan-peng, YU Yun-peng, XU Cong-kang, WANG Jiang-yong. GDOES Depth Resolution Analysis of Flexible Functional Film [J]. VACUUM, 2020, 57(4): 1-5.
[8] LI Jian, TONG Hong-hui, DAN Min, JIN Fan-ya, WANG Kun, CHEN Lun-jiang. Analysis of Feasibility for Diamond Like Carbon Films Using as Negative Hydrogen Ions Surface Conversion Materials [J]. VACUUM, 2020, 57(4): 6-10.
[9] ZHANG Shuang, DONG Chuang, MA Yan-ping, DING Wan-yu. Material Characteristics of Thin Films [J]. VACUUM, 2020, 57(4): 11-18.
[10] ZHANG Qing-fang, YI Yong, LUO Jiang-shan. Effect of Sputtering Power on Microstructure of Er Thin Films Deposited by Magnetron Sputtering [J]. VACUUM, 2020, 57(3): 17-20.
[11] LI Xiao-min, WU Ying-tong, BAI Rui, WANG Dong-wei, HUANG Mei-dong. Influence of Annealing Temperature on Microstructure, Wettability of TiO2Films [J]. VACUUM, 2020, 57(3): 21-24.
[12] ZHAO Yu-hui, ZHAO Ji-bin, WANG Zhi-guo, WANG Fu-yu. Research on the Stress Control Methods of Inconel625Nickel-Based Alloys Fabricated by Laser Melting Additive Manufacturing [J]. VACUUM, 2020, 57(3): 73-79.
[13] ZHONG Li, SHEN Li-ru, CHEN Mei-yan, LIU Tong, DAN Min, JIN Fan-ya. Study on Tribological Properties of (Ti, Cr) N Films [J]. VACUUM, 2020, 57(2): 27-32.
[14] XIA Zhu-jie, ZHANG Zhi-guo, WANG Hong-li, SU Yi-fan, TANG Peng, LIN Song-sheng, DAI Jiang-ming, SHI Qianb. Preparation and Electrochromic Properties of WO3 Thin Films [J]. VACUUM, 2020, 57(2): 47-52.
[15] WANG Zhong-lian, REN Shao-peng, YIN Xiao-jun, WANG Rui-sheng, GAO Peng, BAN Chao, HU Wen-wen. Study of Design and Measurement for Variable Filter [J]. VACUUM, 2020, 57(1): 21-25.
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
No Suggested Reading articles found!