欢迎访问沈阳真空杂志社 Email Alert    RSS服务

VACUUM ›› 2021, Vol. 58 ›› Issue (5): 26-31.doi: 10.13385/j.cnki.vacuum.2021.05.03

• Vacuum Technology Application • Previous Articles     Next Articles

Present Situation and Development of Nano Films Deposited by Molecular Layer Deposition

CHEN QIAN, YANG Li-zhen, LIU Zhong-Wei, ZHANG Hai-bao, CHEN Qiang   

  1. Laboratory of Plasma Physics and Materials, Beijing Institute of Graphic Communication, Beijing 102600, China
  • Received:2020-11-05 Online:2021-09-25 Published:2021-09-23

Abstract: With the development of microelectronic technology, lithium-ion batteries and solar cells, especially the need of nano polymer films, are becoming higher and higher. Since the traditional deposition method can not meet the requirements, it is imperative to find a new method to deposit polymer. Molecular layer deposition(MLD) is a technique similar to atomic layer deposition, which can precisely control the thickness, composition, morphology and shape retention of polymer films. Therefore, MLD can be a new method to prepare polymer films. In this paper, the principle and method of MLD, as well as the development and application in the field of thin film preparation are reviewed. Finally, the challenges and prospects of MLD in the future are forecasted.

Key words: molecular layer deposition, principle, thin film, application

CLC Number: 

  • TQ31
[1] YOSHIMURA T, TATSUURA S, SOTOYAMA W.Polymer films formed with monolayer growth steps by molecular layer deposition[J]. Appl.Phys.Lett, 1991, 59(4): 482-484.
[2] YOSHIMURA T, TATSUURA S, SOTOYAMA W, et al.Quantum wire and dot formation by chemical vapor deposition and molecular layer deposition of one-dimensional conjugated polymer[J]. Appl.Phys.Lett, 1992, 60(3): 268-270.
[3] OLDHAM C J, GONG B, SPAGNOLA J C, et al.Encapsulation and chemical resistance of electrospun nylon nanofibers coated using integrated atomic and molecular layer deposition[J]. J.Electrochem.Soc, 2011, 158(9): D549-D556.
[4] YOSHIMURA T, OSHIMA A, KIM D.Il, et al. Quantum dot formation in polymer wires by three-molecule molecular layer deposition(MLD) and applications to electro-optic/ photovoltaic devices[J]. In ECS Transactions; ECS, 2009, 25(4): 15-25.
[5] GRILLO F, BUI H V, MOULIJN J A, et al.Understanding and controlling the aggregative growth of platinum nanoparticles in atomic layer deposition: an avenue to size selection[J]. J.Phys.Chem.Lett, 2017, 8: 975-983.
[6] KALOYEROS A E, GOFF J, ARKLES B.Emerging molecular and atomic level techniques for nanoscale applications[J]. ECS Interface, 2018, 27(4): 61-65.
[7] DAMERON A A, SEGHETE D, BURTON B B, et al.Molecular layer deposition of alucone polymer films using trimethylaluminum and ethylene glycol[J]. Chem.Mater, 2008, 20(10): 3315-3326.
[8] ZHOU H, BENT S F.Fabrication of organic interfaciallayers by molecular layer deposition: present status and future opportunities[J]. J. Vac. Sci. Technol., A, 2013, 31(4):040801.
[9] PUTKONEN M, HARJUOJA J, SAJAVAARA T, et al.Atomic layer deposition of polyimide thin films[J]. J.Mater.Chem, 2007, 17(7): 664-669.
[10] DU Y, GEORGE S M.Molecular layer deposition of nylon 66 films examined using in situ FTIR spectroscopy[J]. J.Phys.Chem.C, 2007, 111(24): 8509-8517.
[11] PENG Q, EFIMENKO K, GENZER J, et al.Oligomer orientation in vapor-molecular-layer-deposited alkyl-aromatic polyamide films[J]. Langmuir, 2012, 28(28): 10464-10470.
[12] IVANOVA T V, MAYDANNIK P S, CAMERON D C. Molecular layer deposition of polyethylene terephthalate thin films[J]. J.Vac.Sci.Technol.A, 2012, 30(1): 01A121.
[13] LUSHINGTON A, LANGFORD C, LIU J, et al.Orientation and ordering of organic and hybrid inorganic-organic polyurea films using molecular layer deposition[J]. J.Phys.Chem.C, 2017, 121(21): 11757-11764.
[14] UDDIN S M N, NAGAO Y. Multilayer growth of porphyrin-based polyurea thin film using solution-based molecular layer deposition technique[J]. Langmuir, 2017, 33(44): 12777-12784
[15] CLOSSER R G, BERGSMAN D S, BENT S F.Molecular layer deposition of a highly stable silicon oxycarbide thin film using an organic chlorosilane and water[J]. ACS Appl.Mater.Interfaces, 2018, 10: 24266-24274.
[16] YOON B, LEE Y, DERK A, et al.Molecular layer deposition of conductive hybrid organic-inorganic thin films using diethylzinc and hydroquinone[J]. ECS Trans., 2011, 33(27): 191-195.
[17] CHOI D W, YOO M, LEE H M, et al.A study on the growth behavior and stability of molecular layer deposited alucone films using diethylene glycol and trimethyl aluminum precursors,and the enhancement of diffusion barrier properties by atomic layer deposited Al2O3 capping[J]. ACS Applied Materials & Interfaces, 2016, 8(19): 12263-12271.
[18] SUN F B, DUAN Y, YANG Y Q.Fabrication of tunable[Al2O3: Alucone]thin-film encapsulations for top-emitting organic light-emitting diodes with high performance optical and barrier properties[J]. Organic Electronics, 2014, 15(10): 2546-2552.
[19] PARK Y S, CHOI S E, KIM H, et al, Fine-tunable absorption of uniformly aligned polyurea thin films for optical filters using sequentially self-limited molecular layer deposition[J]. ACS applied materials & interfaces, 2016, 8(18): 11788-11795.
[20] TYNELL T, YAMAUCHI H, KARPPINEN, M. Hybrid inorganic-organic superlattice structures with atomic layer deposition/molecular layer deposition[J]. Journal of Vacuum Science & Technology A: Vacuum, Surfaces,Films, 2014, 32(1): 01A105.
[21] GIRI A, NIEMELÄ J P, SZWEJKOWSKI C J, et al.Reduction in thermal conductivity and tunable heat capacity of inorganic/organic hybrid superlattices[J]. Physical Review B, 2016, 93(2): 024201.
[22] GIEDRAITYTE Z, JOHANSSON L S, KARPPINEN M.ALD/MLD fabrication of luminescent Eu-organic hybrid thin films using different aromatic carboxylic acid components with N and O donors[J]. RSC Advances, 2016, 6(105): 103412-103417.
[23] GIEDRAITYTE Z, SAINIO J, HAGEN D, et al.Luminescent metal-nucleobase network thin films by atomic/molecular layer deposition[J]. The Journal of Physical Chemistry C, 2017, 121(32): 17538-17545.
[24] ABDULAGATOV A I, TERAUDS K, TRAVIS J J, et al.Pyrolysis of titanicone molecular layer deposition films as precursors for conducting TiO2/carbon composite films[J]. The Journal of Physical Chemistry C, 2013, 117(34): 17442-17450.
[25] LIU J, YOON B, KUHLMANN E, et al.Ultralow thermal conductivity of atomic/molecular layer-deposited hybrid organic-inorganic zincone thin films[J]. Nano Letters, 2013, 13(11): 5594-5599.
[26] YANG F, BREDE J, ABLAT H, et al.Reversible and irreversible reactions of trimethylaluminum with common organic functional groups as a model for molecular layer deposition and vapor phase infiltration[J]. Advanced Materials Interfaces, 2017, 4(18): 1700237-1700247.
[27] GRIMME S.Semiempirical GGA-type density functional constructed with a long-range dispersion correction[J]. Journal of Computational Chemistry, 2006, 27(15): 1787-1799.
[28] SHENG J, PARK E J, SHONG B, et al.Atomic layer deposition of an indium gallium oxide thin film for thin-film transistor applications[J]. ACS Applied Materials & Interfaces, 2017, 9(28): 23934-23940.
[29] CHOUDHURY D, RAJARAMAN G, SARKAR S K.Stability of molecular layer deposited zincone films:experimental and theoretical exploration[J]. RSC Advances, 2015, 5(38): 29947-29952.
[30] 王潇. 基于原子层与分子层沉积相结合的混合薄膜封装技术[D]. 长春: 吉林大学, 2016.
[31] 王浩然. 基于低温原子层沉积的钙钛矿太阳能电池薄膜封装[D]. 长春: 吉林大学, 2020
[32] QIN L J, YAN N, HAO H X, et al.Surface engineering of zirconium particles by molecular layer deposition:significantly enhanced electrostatic safety at minimum loss of the energy density[J]. Applied Surface Science, 2018, 436: 548-555.
[33] 秦利军, 龚婷, 闫宁, 等. 原子层沉积技术在含能材料表面修饰中的应用研究进展[J]. 火炸药学报, 2019, 42(5): 425-131.
[34] MENG X.An overview of molecular layer deposition for organic and organic-inorganic hybrid materials: mechanisms, growth characteristics: and promising applications[J]. J.Mater.Chem.A, 2017, 5(35): 18326-18378.
[35] SUN Y, ZHAO Y, WANG J, et al.A novel organic “polyurea” thin film for ultralong-life lithium-metal anodes via molecular-layer deposition[J]. Adv.Mater, 2019, 31(4): 1806541.
[36] LI X, LUSHINGTON A, SUN Q, et al.Safe and durable high temperature lithium-sulfur batteries via molecular layer deposited coating[J]. Nano Lett, 2016, 16(6): 3545-3549.
[37] ZHOU H, TONEY M, BENT F, et al.Cross-linked ultrathin polyurea films via molecular layer deposition[J]. 2013, 46(14): 5638-5643.
[38] XIONG S, SHENG T, KONG L, et al.Enhanced performances of polypropylene membranes by molecular layer deposition of polyimide[J]. Chin.J.Chem.Eng, 2016, 24(7): 843-849.
[39] SHENG T, CHEN H, XIONG S, et al.Atomic layer deposition of polyimide on microporous polyethersulfone membranes for enhanced and tunable performances[J]. AICHE J, 2014, 60(10): 3614-3622.
[40] TORNQVIST R, KORPELA S.On the aging of ZnS: Mn electroluminescent thin films grown by the atomic layer epitaxy technique[J]. Journal of Crystal Growth. 1982, 59(1-2): 395-398.
[1] WEI Meng-yao, WANG Hui, HAN Wen-fang, WANG Hong-li, SU Yi-fan, TANG Chun-mei, DAI Ming-jiang, SHI Qian. Study on Electrochromic Properties of Tungsten Oxide Films Deposited by Medium Frequency Magnetron Sputtering [J]. VACUUM, 2021, 58(5): 50-56.
[2] ZHANG Xiao-xia, DENG Jin-xiang, KONG Le, LI Rui-dong, YANG Zi-shu, ZHANG Jie. Preparation and Study of Si-doped β-Ga2O3 Thin Films with Different Content [J]. VACUUM, 2021, 58(5): 57-61.
[3] JIANG Kai-yin, YANG Li-zhen, LIU Zhong-wei, ZHANG Hai-bao, CHEN Qiang. Ion Energy and its Diagnosis in Helicon Plasma Source [J]. VACUUM, 2021, 58(4): 67-76.
[4] YANG Zi-shu, DUAN Ping, DENG Jin-xiang, ZHANG Xiao-xia, ZHANG Jie, YANG Qian-qian. Preparation and Study of Mg-doped β-Ga2O3 Thin Films with Different Content [J]. VACUUM, 2021, 58(3): 30-34.
[5] ZHANG Xin-hui, LI Qing-xiao. Effect of Vacuum Heat Treatment on Structure and Photoelectric Properties of AZO Film [J]. VACUUM, 2021, 58(3): 45-50.
[6] TIAN Li-cheng, WANG Shang-min, GAO Jun, MENG Wei, TIAN Kai, WU Chen-chen. Development and Application of Micro-electric Propulsion System [J]. VACUUM, 2021, 58(2): 66-75.
[7] ZHANG Yu-chen, ZHANG Hai-bao, CHEN Qiang. Review on Semi-Conductive ZnO Thin Film Prepared by HiPIMS [J]. VACUUM, 2021, 58(1): 72-77.
[8] WANG Xun. Vacuum Measurement and Application for Aerospace [J]. VACUUM, 2021, 58(1): 15-18.
[9] GUO Zhi-shuai, FEI Shu-guo, YIN Xiao-jun, GAO Peng, ZHAO Shuai-feng, WANG Yin-he, SONG Guang-hui. Design and Coating Technology of Optical Filter for Infrared Thermometry Imaging [J]. VACUUM, 2020, 57(6): 18-22.
[10] ZHANG Shuang, DONG Chuang, MA Yan-ping, DING Wan-yu. Material Characteristics of Thin Films [J]. VACUUM, 2020, 57(4): 11-18.
[11] ZHANG Qing-fang, YI Yong, LUO Jiang-shan. Effect of Sputtering Power on Microstructure of Er Thin Films Deposited by Magnetron Sputtering [J]. VACUUM, 2020, 57(3): 17-20.
[12] XIA Zhu-jie, ZHANG Zhi-guo, WANG Hong-li, SU Yi-fan, TANG Peng, LIN Song-sheng, DAI Jiang-ming, SHI Qianb. Preparation and Electrochromic Properties of WO3 Thin Films [J]. VACUUM, 2020, 57(2): 47-52.
[13] ZHAO Teng-jiao, JIN Nan, LIN Bin, WANG Zhi-guo. Application Research of SLM Metal 3D Printing Technology in Main Pump Prototype Test [J]. VACUUM, 2019, 56(6): 64-67.
[14] LIU Zhao, XING Hong-shuo, SU Jia-hao, ZHANG Jun-shen, LIANG Shuai, XIE Yuan-hua, HAN Jin. Discussion on Present Situation and Development Trend of Vacuum Elevator [J]. VACUUM, 2019, 56(6): 54-59.
[15] LIAO Rong, DENG Yong-jian, WANG Jia-ju, ZHAO Fei-lan, ZHENG Ruo-qian, LIU Hui-jun, KE Jia-chong. Preparation and Properties of High Dielectric Hafnium Oxide Thin Film [J]. VACUUM, 2019, 56(5): 52-55.
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
No Suggested Reading articles found!