欢迎访问沈阳真空杂志社 Email Alert    RSS服务

VACUUM ›› 2025, Vol. 62 ›› Issue (1): 44-48.doi: 10.13385/j.cnki.vacuum.2025.01.07

• Thin Film • Previous Articles     Next Articles

Study on the Bonding Performance and Wear Resistance of TiN and TiAlN Coatings on the Annealed Steel Substrate

ZHAO Xingzhong   

  1. Chengdu Tianao Technology Development Co., Ltd., Chengdu 610036, China
  • Received:2024-04-22 Online:2025-01-25 Published:2025-02-10

Abstract: The TiN and TiAlN coatings were deposited on annealed alloy steel by cathodic arc ion plating. The structure, composition and phase composition of the coatings were analyzed by scanning electron microscopy and X-ray diffractometer, the hardness of the coating was tested by micro Vickers hardness tester, the bonding properties of the coating were evaluated by indentation method, and the wear resistance of the coating was tested by reciprocating ball-disk friction and wear test. The results show that the surface of the TiN and TiAlN coatings are smooth. There are many "droplet" defects at the surface of TiAlN coating. Both TiN and TiAlN coatings grow in a preferred orientation. The preferred crystal plane of TiN coating is （111）, and that of the TiAlN coating is （200）. The hardness of annealed alloy steel coated with TiN and TiAlN coatings increases by more than 3 and 6 times, respectively. Although the hardness of TiAlN coating is significantly higher than that of the TiN coating and the friction coefficient is lower than that of the TiN coating, the TiAlN coating peeled off during wear due to the poor bonding performance between TiAlN coating and annealed alloy steel, which deteriorated the wear resistance of the alloy steel. The TiN coating can protect the annealed alloy steel substrate and significantly improve its surface wear resistance.

Key words: annealed alloy steel, cathodic arc ion plating, coating, bonding performance, abrasion resistance

CLC Number:  TG174.4

[1] 白双锋,刘雪辉,许立坤,等. SiO2粒径对Ni-Co-SiO2复合镀层性能的影响[J].材料开发与应用,2021, 36(6): 12-20.
[2] 张梦瑶,田晓东,高顺. 5083铝合金复合电镀镍-碳化硅-二硫化钼的显微组织和耐磨性[J].电镀与涂饰,2019, 38(16): 843-846.
[3] 喻岚,汪镇涛,熊梧尧,等. 9Cr18不锈钢表面不同耐磨镀层的微观结构及耐磨性[J].电镀与精饰, 2023, 45(11): 1-8.
[4] 刘李,张哲晨,靳广虎,等. Ni-P-SiC镀层及其摩擦磨损特性研究[J].金属功能材料, 2023, 30(5): 123-129.
[5] 金杰,陈蕴博,高克玮.不同族金属离子注入对Cr4Mo4V摩擦磨损性能的影响[J].中国表面工程,2014,27(2):24-30.
[6] 孙佩玲. M50钢喷丸与等离子体离子注入复合改性层组织结构及性能[D].哈尔滨:哈尔滨工业大学,2015.
[7] DODD A, KINDE R J, TORP B, et al.The effect of ion implantation on the fatigue life and corrosion resistance of M50 steel bearings[J]. Surface & Coatings Technology, 1995, 74:754-759.
[8] 刘汇河,宋海涛,姚颖才,等.8Cr4Mo4V异形滚子盐浴软氮化工艺试验[J].轴承, 2020(4):15-18.
[9] 单嗣宏. M50钢离子源辅助渗氮层的组织与性能[D].哈尔滨:哈尔滨工业大学, 2018.
[10] 解芳,高金杰,翟长生,等.重熔温度对GCr15轴承钢表面感应重熔镍基涂层微观组织性能的影响[J].表面技术, 2021,50(7):250-257.
[11] 熊晓晨,燕怒,姜雨.表面爆炸喷涂WC涂层对GCr15轴承钢抗疲劳性能的影响[J].机械工程材料, 2018,42(2):74-77.
[12] 熊晓晨,燕怒,韩晓琪.轴承钢磁控溅射TiN涂层工艺参数对其性能的影响[J].表面技术,2014,43(1):67-70.
[13] TANG B Y, WANG Y H, WANG L P, et al.Adhesion strength of TiN films synthesized on GCr15-bearing steel using plasma immersion ion implantation and deposition[J]. Surface & Coatings Technology, 2004,186(1-2):153-156.
[14] 张权,许雨翔,王启民,等. 先进复合物理气相沉积技术制备高性能硬质涂层[J].工具技术,2020,54(7):3-7.
[15] 李斌. 铸钢件热处理技术分析与研究[J].现代制造技术与装备,2018(3):60.
[16] 路筱歆,胡树兵,姚南,等.模具钢TiAlN和TiAlSiN涂层的制备及性能[J].材料热处理学报,2022,43(4):146-155.
[17] 卢龙,张会霞,刘崇林,等.40Cr钢表面离子镀TiAlN涂层的膜基结合力研究[J].铸造技术,2015,36(12):2889-2891.
[18] 田颖萍,范洪远,成靖文.氮氩流量比对磁控溅射TiN薄膜生长织构的影响[J].表面技术, 2012, 41(3): 19-25.
[19] GERTH J, WIKLUND U.The influence of metallic interlayers on the adhesion of PVD TiN coatings on high-speed steel[J]. Wear, 2008, 264(9-10): 885-892.
[20] CARVALHO N J M, ZOESTBERGEN E, KOOI B J, et al. Stress analysis and microstructure of PVD monolayer TiN and multilayer TiN/(Ti,Al)N coatings[J]. Thin Solid Films, 2003, 429(1-2): 179-189.
[1] LI Tingyue, WANG Xin, ZHEN Zhen, LI Na, XU Zhenhua. Effect of Different Bond Layers on Thermal Shock Behavior of Yb2O3 Modified Gd2Zr2O7 Thermal Barrier Coatings [J]. VACUUM, 2025, 62(1): 26-36.
[2] TANG Zheng. Study on Film Formation Uniformity of Horizontally Moving Substrate by Array Evaporation Sources [J]. VACUUM, 2024, 61(6): 21-25.
[3] LI Ting-yue, WANG Xin, ZHEN Zhen, LI Na, XU Zhen-hua. Microstructure and Thermal Cycling Properties of Yb2O3 Modified Gd2Zr2O7 Thermal Barrier Coatings [J]. VACUUM, 2024, 61(5): 21-29.
[4] LI Xiang, JIANG Xiao-jiao, ZHAN Chun-ming, LIU Ang, SUN Ning, LI Jia-ping. Research on Design Method of Liquid Cooled Heater for Vacuum Coating Equipment Based on System Regression Model [J]. VACUUM, 2024, 61(4): 6-11.
[5] ZHAO Fan, XIANG Yan-xiong, ZOU Chang-wei, YU Yun-jiang, LIANG Feng. Application of Magnetron Sputtering Deposition Technology for （Cr,Ti,Al）N Coatings [J]. VACUUM, 2024, 61(4): 22-29.
[6] MAO Xin, FENG Si-qing, LIU Peng, PENG Xue-bing, WU Huan. Test of Outgassing Rates of Threaded Fasteners with Copper Anti-seize Coating [J]. VACUUM, 2024, 61(4): 80-84.
[7] LIU Yu-zhuo, WANG Xin, LI Na, ZHEN Zhen, XU Zhen-hua. Influence of Critical CVD Processing Parameters on High Temperature Protective Performance of (Ni,Pt)Al Coatings [J]. VACUUM, 2024, 61(3): 63-69.
[8] LI Can-lun, NI Jun, GUO Teng, HAN Wei, WANG Fei, QI Song-song, LI Hui, FAN Xiao-peng, FAN Qiu-lin. Research on Optical Properties of CPI Film Second Surface Mirror [J]. VACUUM, 2024, 61(3): 70-73.
[9] XIONG Tian-nong, GAO Peng, WANG Rui-sheng, REN Shao-peng, ZHAO Shuai-feng, YIN Xiao-jun. Analysis of the New Contents in GB/T 26332 Optics and Photonics-Optical Coatings [J]. VACUUM, 2024, 61(3): 74-78.
[10] HUANG Guang-hong, ZHEN Zhen, WANG Xin, MU Ren-de, HE Li-min, XU Zhen-hua. Thermophysical and Thermal Cycling Properties of Multi-element Rare Earth Doped YSZ Thermal Barrier Coatings [J]. VACUUM, 2024, 61(2): 1-9.
[11] LI Can-min, DONG Zhong-lin, XIA Zheng-wei, ZHANG Xin-feng, WEI Rong-hua. Microstructure and Properties of TiCr-based Nanocomposite Coatings by Plasma Enhanced Magnetron Sputtering [J]. VACUUM, 2024, 61(2): 10-15.
[12] LIU Bo-wen, GAO Peng, WANG Rui-sheng, ZHAO Shuai-feng, REN Shao-peng, DONG Ming, CHEN Yi-fan, QIN Rui. Review on Interference Filters for Raman Detection Instruments [J]. VACUUM, 2023, 60(6): 37-41.
[13] LI Can-min, ZHANG Xin-feng, WEI Rong-hua. The Anti-erosion (corrosion) Properties of TiCr-based Nanocomposite Coatings by Plasma Enhanced Magnetron Sputtering [J]. VACUUM, 2023, 60(5): 37-41.
[14] ZHANG Yan-peng, CAO Zhi-qiang, FU Qiang, CAO Lei, LIU Xu. Study of the Influence of Process Parameters of Copper Coating Fabricated by Roll to Roll Machine on Electronic Property of Composite Current Collector [J]. VACUUM, 2023, 60(4): 8-12.
[15] ZHANG Bin, CAI Yan, ZHANG Tao, CHANG Zhen-dong, ZENG Ling-yu, MU Ren-de. Effect of Incident Angle under Deposition on the Morphology and Properties of Thermal Barrier Coatings [J]. VACUUM, 2023, 60(3): 5-11.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
[1] LI De-tian, CHENG Yong-jun, ZHANG Hu-zhong, SUN Wen-jun, WANG Yong-jun, SUN Jian, LI Gang, . Preparations and applications of carbon nanotube field emitters[J]. VACUUM, 2018, 55(5): 1 -9 .
[2] ZHOU Bin-bin, ZHANG jian, HE Jian-feng, DONG Chang-kun. Carbon nanotube field emission cathode based on direct growth technique[J]. VACUUM, 2018, 55(5): 10 -14 .
[3] CHAI Xiao-tong, WANG Liang, WANG Yong-qing, LIU Ming-kun, LIU Xing-zhou, GAN Shu-yi. Operating parameter data acquisition system for single vacuum pump based on STM32F103 microcomputer[J]. VACUUM, 2018, 55(5): 15 -18 .
[4] LI Min-jiu, XIONG Tao, JIANG Ya-lan, HE Yan-bin, CHEN Qing-chuan. 20kV high voltage based on double transistor forward converter pulse power supply for metal deburring[J]. VACUUM, 2018, 55(5): 19 -24 .
[5] LIU Yan-wen, MENG Xian-zhan, TIAN Hong, LI Fen, SHI Wen-qi, ZHU Hong, GU Bing. Test of ultra high vacuum in space traveling-wave tube[J]. VACUUM, 2018, 55(5): 25 -28 .
[6] XU Fa-jian, WANG Hai-lei, ZHAO Cai-xia, HUANG Zhi-ting. Application of chemical gases vacuum-compression recovery system in environmental engineering[J]. VACUUM, 2018, 55(5): 29 -33 .
[7] XIE Yuan-hua, HAN Jin, ZHANG Zhi-jun, XU Cheng-hai. Discussion on present situation and development trend of vacuum conveying[J]. VACUUM, 2018, 55(5): 34 -37 .
[8] SUN Li-zhi, YAN Rong-xin, LI Tian-ye, JIA Rui-jin, LI Zheng, SUN Li-chen, WANG Yong, WANG Jian, . Research on distributing law of Xenon in big accumulation chamber[J]. VACUUM, 2018, 55(5): 38 -41 .
[9] HUANG Si, WANG Xue-qian, MO Yu-shi, ZHANG Zhan-fa, YING Bing. Experimental study on similarity law of liquid ring compressor performances[J]. VACUUM, 2018, 55(5): 42 -45 .
[10] CHANG Zhen-dong, MU Ren-de, HE Li-min, HUANG Guang-hong, LI Jian-ping. Reflectance spectroscopy study on TBCs prepared by EB-PVD[J]. VACUUM, 2018, 55(5): 46 -50 .
辽ICP备06004570号-4
Copyright © VACUUM, All Rights Reserved.
Tel: （024）24134406 24110136 24121929　Fax: （024） 24121929　E-mail: zkzk1964@126.com
Powered by Beijing Magtech Co. Ltd