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真空 ›› 2020, Vol. 57 ›› Issue (2): 33-39.doi: 10.13385/j.cnki.vacuum.2020.02.07

• 薄膜 • 上一篇    下一篇

冷作模具钢等离子渗镀CrVN复合涂层摩擦磨损性能研究*

方波1,2, 张林2, 蔡飞2, 张世宏1,2   

  1. 1.安徽工业大学材料科学与工程学院,安徽 马鞍山 243002;
    2.安徽工业大学现代表界面工程研究中心,安徽 马鞍山 243002
  • 收稿日期:2019-02-13 出版日期:2020-03-25 发布日期:2020-04-24
  • 通讯作者: 张世宏,教授。
  • 作者简介:方波(1993-),男,安徽省六安市人,硕士。
  • 基金资助:
    *国家自然科学基金(51522502);安徽省重点研发计划(1804b06020370)资助项目

Study on Wear Properties of Duplex-Treated CrVN Composite Coatings by Plasma Nitriding and Arc Ion Plating

FANG Bo1,2, ZHANG Lin2, CAI Fei2, ZHANG Shi-hong1,2   

  1. 1.School of Materials Science and Engineering, Anhui University of Technology, Ma′anshan 243002, China;
    2.Research Center of Modern Surface and Interface Engineering, Anhui University of Technology, Ma’anshan 243002, China
  • Received:2019-02-13 Online:2020-03-25 Published:2020-04-24

摘要： 采用等离子渗镀技术在DC 53冷作模具钢表面制备CrN和CrVN复合涂层,利用X射线衍射仪(XRD)、X射线光电子能谱(XPS)、扫描电镜(SEM)、显微硬度计和摩擦磨损试验机,对比研究了两种涂层的组织结构、力学性能以及摩擦磨损性能。结果表明:所制备的CrN和CrVN涂层均为面心立方 (fcc) 结构,并呈现 (111) 择优取向,其中CrVN涂层形成了以fcc-CrN相为基础的CrVN固溶体结构。CrN涂层中掺入V抑制了柱状晶生长,涂层结构更加致密,硬度和结合力明显提高,摩擦系数及磨损率降低。CrVN涂层表面粗糙度较低,并在摩擦过程中生成具有自润滑性的VO2,涂层抗粘铝性能得到改善。

关键词: 冷作模具, CrVN涂层, 微观结构, 摩擦磨损, 抗粘附性

Abstract: Duplex-treated CrN and CrVN composite coatings were prepared on DC 53 cold work die steel substrates by plasma nitriding and arc ion plating. The microstructure, mechanical and wear properties of coatings were investigated by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), microhardness tester and tribometer, respectively. The results showed that the as-deposited coatings were fcc structures with a (111) preferred orientation. The CrVN solid solution structure based on the fcc-CrN phase was obtained in CrVN coating. Compared to the CrN coating, the columnar grain growth was suppressed with the addition of V and the CrVN coating became denser. The microhardness and adhesive strength of V-doped CrN coating were obviously improved, while the friction coefficient and wear rate of the coating were reduced. The sticking resistance of aluminium was enhanced for CrVN coating due to the low surface roughness and the formation of self-lubricating VO2 during the wear process.

Key words: cold work mould, CrVN coatings, microstructure, tribological properties, anti-sticking

中图分类号: 

  • TG17
[1] Lagunacamacho J R, Cruzmendoza L A, Anzelmettizaragoza J C, et al.Solid particle erosion on coatings employed to protect die casting molds[J]. Progress in Organic Coatings, 2012, 74(4):750-757.
[2] 张姣姣, 王铁钢, 阎兵. 复合磁控溅射Zr-B-N涂层微结构的控制及性能研究[J]. 真空科学与技术学报, 2018,38(6):479-485.
[3] 高倩, 黄美东, 王小龙,等. 脉冲偏压占空比对复合离子镀(Cr,Al)N薄膜结构和力学性能的影响[J]. 真空, 2015,52(3):7-10.
[4] Vetter J.Vacuum arc coatings for tools: potential and application[J]. Surface & Coatings Technology, 1995, 76:719-724.
[5] Reiter A E, Derflinger V H, Hanselmann B, et al.Investigation of the properties of Al1-xCrxN coatings prepared by cathodic arc evaporation[J]. Surface & Coatings Technology, 2005, 200(7):2114-2122.
[6] Altan T, Lilly B, Yen Y C, et al.Manufacturing of dies and molds[J]. CIRP Annals - Manufacturing Technology, 2001, 50(2):404-422.
[7] 孙国威, 陈泽昊, 李云珂,等. 靶基距对杂化离子镀TiCN薄膜结构和性能的影响[J]. 真空, 2018,55(2):20-22.
[8] Li W Z, Chen Q Z, Polcar T, et al.Influence of Zr alloying on the mechanical properties, thermal stability and oxidation resistance of Cr-Al-N coatings[J]. Applied Surface Science, 2014, 317:269-277.
[9] Uchida M, Nihira N, Mitsuo A, et al.Friction and wear properties of CrAlN and CrVN films deposited by cathodic arc ion plating method[J]. Surface & Coatings Technology, 2004, 177:627-630.
[10] 贾丛丛, 李沛, 葛芳芳,等.偏压对Cr-Si-N涂层的结构与性能的影响[J]. 真空科学与技术学报, 2016, 36(4):418-424.
[11] Magnéli A.Structures of the ReO3-type with recurrent dislocations of atoms:‘homologous series’of molybdenum and tungsten oxides[J]. Acta Crystallographica, 1953, 6(6):495-500.
[12] 金浩, 李德元, 卢旭东. V含量对磁控溅射CrAlVN涂层微观结构及力学和摩擦学性能的影响[J]. 材料导报, 2016, 30(20):53-56.
[13] Bobzin K, Bagcivan N, Ewering M, et al.DC-MSIP/HPPMS (Cr,Al,V)N and (Cr,Al,W)N thin films for high-temperature friction reduction[J]. Surface & Coatings Technology, 2011, 205(8):2887-2892.
[14] Fateh N, Fontalvo G A, Gassner G, et al.Influence of high-temperature oxide formation on the tribological behaviour of TiN and VN coatings[J]. Wear, 2007, 262(9):1152-1158.
[15] 谢飞,何家文.高速钢W18Cr4V离子氮碳共渗层组织对TiN膜与基体结合强度的影响[J],金属学报,2000, 36(10): 1099-1103.
[16] Fei C, Ying G, Wei F, et al.Improved adhesion and cutting performance of AlTiSiN coatings by tuning substrate bias voltage combined with Ar ion cleaning pre-treatment[J]. Ceramics International, 2018, 44: 18894-18902.
[17] Mayrhofer P H, Mitterer C, Htman L, et al.Microstructural design of hard coatings[J]. Progress in Materials Science, 2006, 51(8):1032-1114.
[18] 喻利花, 王蕊, 许俊华. 基体负偏压对W-C-N薄膜摩擦磨损性能的影响[J]. 材料热处理学报, 2013, 34(4):166-171.
[19] Gautier C, Moussaoui H, Elstner F, et al. Comparative study of mechanical and structural properties of CrN films deposited by d.c. magnetron sputtering and vacuum arc evaporation[J]. Surface & Coatings Technology, 1996, 86-87(96):254-262.
[20] 许俊华, 曹峻, 喻利花. 磁控溅射制备TiCN复合膜的微结构与性能[J]. 中国有色金属学报, 2012,22(11):3123-3128.
[21] Allen G C, Tucker P M, Wild R K.X-ray photoelectron auger electron spectroscopic study of the initial oxidation of chromium metal[J]. Journal of Cheminform, 1978, 9(34):1126-1140.
[22] Sleigh C, Pijpers A P, Jaspers A, et al.On the determination of atomic charge via ESCA including application to organometallics[J]. Journal of Electron Spectroscopy & Related Phenomena, 1996, 77(1):41-57.
[23] Nishimura O, Yabe K, Iwaki M.X-ray photoelectron spectroscopy studies of high-dose nitrogen ion implanted-chromium: a possibility of a standard material for chemical state analysis[J]. Journal of Electron Spectroscopy & Related Phenomena, 1989, 49(3):335-342.
[24] Tougaard S.Quantitative analysis of the inelastic background in surface electron spectroscopy[J]. Surface & Interface Analysis, 1988, 11(9):453-472.
[25] Wagner C D.Sensitivity factors for XPS analysis of surface atoms[J]. Journal of Electron Spectroscopy & Related Phenomena, 1983, 32(2):99-102.
[26] NIST Standard Reference Database 20: Version 4.1[DB/OL]. (2012-9-15)[2018-1-29]. https://srdata.nist.gov/xps/.
[27] Nag N K, Massoth F E.ESCA and gravimetric reduction studies on V/Al2O3 and V/SiO2 catalysts[J]. Journal of Catalysis, 1990, 124(1):127-132.
[28] Musil J, Kunc F, Zeman H, et al.Relationships between hardness, Young's modulus and elastic recovery in hard nanocomposite coatings[J]. Surface & Coatings Technology, 2002, 154(2):304-313.
[29] 朱晓东, 米彦郁, 胡奈赛,等. 膜基结合强度评定方法的探讨―划痕法、压入法、接触疲劳法测定的比较[J]. 中国表面工程, 2002, 15(4):28-31.
[30] Wang T G, Jeong D, Kim S H, et al.Study on nanocrystalline Cr2O3 films deposited by arc ion plating: I. composition, morphology, and microstructure analysis[J]. Surface & Coatings Technology, 2012, 206(10):2629-2637.
[31] 周军, 樊湘芳, 李涛,等. 弧电流对多弧离子镀TiAlN涂层表面形貌和性能的影响[J]. 材料保护, 2018,51(6):74-78.
[32] 董标, 毛陶杰, 陈汪林,等. Al/Cr原子比对AlCrTiSiN多元复合刀具涂层微观结构及切削性能的影响[J]. 中国表面工程, 2016, 29(5):49-55.
[33] Mouni R, Sourav G, Milan K N, Solvothermal synthesis of Cr2O3 nanocubes via template-free route[J]. Materials Chemistry and Physics, 2015,159:101-106.
[34] Singh J, Verma V, Kumar R.Preparation and structural, optical studies of Al substituted chromium oxide (Cr2O3) nanoparticles[J]. Vacuum, 2019,159: 282-286.
[35] Pan M, Liu J, Zhong H, et al.Raman study of the phase transition in VO2 thin films[J]. Journal of Crystal Growth, 2004, 268(1):178-183.
[36] Ovcharenko A, Halperin G, Etsion I.In situ and real-time optical investigation of junction growth in spherical elastic-plastic contact[J]. Wear, 2008, 264(11):1043-1050.
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