欢迎访问沈阳真空杂志社 Email Alert    RSS服务

VACUUM ›› 2022, Vol. 59 ›› Issue (5): 1-6.doi: 10.13385/j.cnki.vacuum.2022.05.01

• Thin Film •     Next Articles

Preparation and Properties of Zr55Cu30Al10Ni5 Amorphous Thin Films

XIN Xian-feng1, LIU Lin-gen1, LIN Guo-qiang1, DONG Chuang1,2, DING Wan-yu2, ZHANG Shuang2, WANG Qi-zhen2, LI Jun2, WAN Peng3   

  1. 1. Dalian University of Technology, Dalian 116024, China;
    2. Dalian Jiaotong University, Dalian 116028, China;
    3. Foshan Shunde Midea Electrical Heating Appliances Manufacturing Co., Ltd., Foshan 528300, China
  • Received:2021-11-15 Online:2022-09-25 Published:2022-09-28

Abstract: Amorphous alloy films have been widely investigated because of their excellent properties such as non-stick and corrosion resistance, which are especially prominent for bulk-metallic-glass-forming Zr55Cu30Al10Ni5 composition. In this work, amorphous alloy films are prepared by magnetron sputtering using Zr55Cu30Al10Ni5 bulk metallic glass as the target. The effects of different sputtering power on the mechanical properties, non-stick, corrosion resistance and surface roughness of the films were studied. The results show that high-quality amorphous films, as evaluated by mechanical properties, non-stick, and corrosion resistance, can be obtained at a magnetron sputtering power range from 75W to 165W, with hardness of ~9.2GPa, modulus of elasticity of ~164GPa, hardness-to-elasticity ratio of ~0.055, self-corrosion current density of ~1.16μA·cm-2, self-corrosion potential of -241.27mV, and the maximum wetting angle of 104°. Such data are generally comparable with the reported ones(the hardness is even higher), confirming a good potential for non-stick and corrosion resisting purposes.

Key words: Zr-based amorphous alloy, thin film, magnetron sputtering, non-stick, corrosion resistance

CLC Number: 

  • TG174.4
[1] INOUE A, ZHANG W, TSURUI T, et al.Unusual room-temperature compressive plasticity in nanocrystal-toughened bulk copper-zirconium glass[J]. Philosophical Magazine Letters, 2005, 85(5): 221-237.
[2] SHEN B, CHANG C, INOUE A.Ni-based bulk glassy alloys with superhigh strength of 3800MPa in Ni-Fe-B-Si-Nb system[J]. Applied Physics Letters, 2006, 88(20): L2248.
[3] CHEN J K, HSIEN W, KAI C, et al.Antimicrobial properties of Zr-Cu-Al-Ag thin film metallic glass[J]. Thin Solid Films, 2014, 245: 98-101.
[4] 王一禾, 杨膺善. 非晶态合金[M]. 北京: 冶金工业出版社, 1989: 45-52.
[5] NASTASI M, SARIS F W, HUNG L S, et al.Stability of amorphous Cu/Ta and Cu/W alloys[J]. Journal of Applied Physics, 1985, 58(8): 3052-3058.
[6] RIVORY J, FRIGERIO J M, HARMELIN M, et al.Preparation of CuxZr1-x metallic glasses by sputtering and their thermal stability,electrical and optical properties[J]. Thin Solid Films, 1982, 89(3): 323-327.
[7] HUANG L J, CHEN Q M, FAN Y D, et al.Formation of an icosahedral phase in ion-irradiated Fe/Cu multilayers[J]. Journal of Physics F: Metal Physics, 1988, 18(5): L69.
[8] NEWCOMB S B, TU K N.Transmission electron microscopic observations of amorphous Ni-Zr alloy formation by solid-state reaction[J]. Applied Physics Letters, 1986, 48(21): 1436-1438.
[9] CHU J P, JANG J, HUANG J C, et al.Thin film metallic glasses: unique properties and potential applications[J]. Thin Solid Films, 2012, 520(16): 5097-5122.
[10] INOUE A.Stabilization of metallic supercooled liquid and bulk amorphous alloys[J]. Acta Materialia, 2000, 48(1): 279-306.
[11] INOUE A, ZHANG T.Fabrication of bulk glassy Zr55Al10Ni5Cu30 alloy of 30mm in diameter by a suction casting method[J]. Materials Transactions-JIM, 1996, 37(2): 185-187.
[12] LOU H B, WANG X D, XU F, et al.73mm-diameter bulk metallic glass rod by copper mould casting[J]. Applied Physics Letters, 2011, 99(5): 051910.
[13] LEE J, HSU K C, TUNG H C, et al.Applying composition control to improve the mechanical and thermal properties of Zr-Cu-Ni-Al thin film metallic glass by magnetron DC sputtering[J]. Surface & Coatings Technology, 2015, 278: 132-137.
[14] KASSA S T, HU C C, LIAO Y C, et al.Thin film metallic glass as an effective coating for enhancing oil/water separation of electrospun polyacrylonitrile membrane[J]. Surface and Coatings Technology, 2019, 368: 33-41.
[15] CHU J P, LEE C M, HUANG R T, et al.Zr-based glass-forming film for fatigue-property improvements of 316L stainless steel: annealing effects[J]. Surface and Coatings Technology, 2011, 205(16): 4030-4034.
[16] CHANG C H, LI C L, YU C C, et al.Beneficial effects of thin film metallic glass coating in reducing adhesion of platelet and cancer cells: clinical testing[J]. Surface Coating Technology, 2018, 344: 312-321.
[17] KERYVIN V, VAILLANT M L, ROUXEL T, et al.Thermal stability and crystallisation of a Zr55Cu30Al10Ni5 bulk metallic glass studied by in situ ultrasonic echography[J]. Intermetallics, 2002, 10(11/12): 1289-1296.
[18] 陈华. Al基准晶的团簇式及其硬弹性能计算[D]. 大连: 大连理工大学, 2014.
[19] CHU J H, LEE J, CHANG C C, et al.Antimicrobial characteristics in Cu-containing Zr-based thin film metallic glass[J]. Surface & Coatings Technology, 2014, 259: 87-93.
[1] WU Shuai, LIU Shuang, QIN Li-zhao, ZHANG Xu, ZHANG Tong-hua, LIAO Bin, WANG Ke-ping. Study on Thermal Stability of CrCN Films Prepared by FCVAD Technology [J]. VACUUM, 2022, 59(5): 14-19.
[2] ZHANG Jian, LI Jian-hao, QI Zhen-hua. Effect of Process Parameters on SiC Film Properties under DC Magnetron Sputtering [J]. VACUUM, 2022, 59(4): 52-55.
[3] ZHANG Hui, Wang Xiao-bo, ZHANG Wei-xin, GONG Chun-zhi, TIAN Xiu-bo. Effect of Substrate Bias Mode on Structure and Hydrogen Resistance of CrN Thin Films [J]. VACUUM, 2022, 59(1): 18-23.
[4] LIAO Guo-jin, YAN Shao-feng, YI Deng-li, DAI Xiao-chun. The Luminescent Property of Al2O3:Ce MFRMS Thin Films Sputtered by Optimal Design of Experiments [J]. VACUUM, 2022, 59(1): 24-28.
[5] LIU Yuan-dong. Study on the Properties of Large-area ZnO Thin Films Fabricated by Magnetron Sputtering Deposition [J]. VACUUM, 2022, 59(1): 29-32.
[6] HE Ping, ZHANG Xu, YANG yang. Study on Magnetron Sputtering Film Process on Inner Wall of Cylinder with Different Matrix Materials [J]. VACUUM, 2021, 58(6): 33-37.
[7] DUAN Shan-Shan, SHI Chang-yong, YANG Li-Zhen, LIU Zhong-wei, ZHANG Hai-bao, CHEN Qiang. The Recent Development and Future of Atomic Layer Deposition of Alumina Thin Films [J]. VACUUM, 2021, 58(6): 13-20.
[8] ZHU Bei-bei, NI Chang, QIN Lin, CHU Jian-ning, CHEN Xiao, XU Jian-feng. Nano Film Deposition Technology Based on Magnetron Sputtering [J]. VACUUM, 2021, 58(6): 21-26.
[9] YANG Zhao, LUO Jun-yao, LI Bao-chang, LI Shu-hua, TA Shi-wo, FU Zhen-xiao, NING Hong-long. Effect of Metallic Multilayer Films on Gold Wire Bonding Properties [J]. VACUUM, 2021, 58(6): 43-47.
[10] CHEN QIAN, YANG Li-zhen, LIU Zhong-Wei, ZHANG Hai-bao, CHEN Qiang. Present Situation and Development of Nano Films Deposited by Molecular Layer Deposition [J]. VACUUM, 2021, 58(5): 26-31.
[11] WEI Meng-yao, WANG Hui, HAN Wen-fang, WANG Hong-li, SU Yi-fan, TANG Chun-mei, DAI Ming-jiang, SHI Qian. Study on Electrochromic Properties of Tungsten Oxide Films Deposited by Medium Frequency Magnetron Sputtering [J]. VACUUM, 2021, 58(5): 50-56.
[12] ZHANG Xiao-xia, DENG Jin-xiang, KONG Le, LI Rui-dong, YANG Zi-shu, ZHANG Jie. Preparation and Study of Si-doped β-Ga2O3 Thin Films with Different Content [J]. VACUUM, 2021, 58(5): 57-61.
[13] FU Xue-cheng, XU Jin-bin, WU Li-ying, HUANG Sheng-li, WANG Ying. Study on Uniformity of Inclined Magnetron Sputtering with Small Circular Plane Target [J]. VACUUM, 2021, 58(4): 1-5.
[14] ZHANG Jian, NIU Xia-bin, LI Jian-hao, QI Zhen-hua. Effect of RF Power and Sputtering Pressure on Al Film Sputtered on Polythylene Terephthalate Substrates [J]. VACUUM, 2021, 58(4): 21-24.
[15] YU Hua-jun, ZHAO Xi-jun, WU Rui-jun. Solutions for Asymmetrical Target Erosion Due to Cross-Cathode Effect [J]. VACUUM, 2021, 58(3): 51-54.
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
[1] LI De-tian, CHENG Yong-jun, ZHANG Hu-zhong, SUN Wen-jun, WANG Yong-jun, SUN Jian, LI Gang, . Preparations and applications of carbon nanotube field emitters[J]. VACUUM, 2018, 55(5): 1 -9 .
[2] ZHOU Bin-bin, ZHANG jian, HE Jian-feng, DONG Chang-kun. Carbon nanotube field emission cathode based on direct growth technique[J]. VACUUM, 2018, 55(5): 10 -14 .
[3] LI Zhi-sheng. Development of ultra large shielded door for infrared calibration in simulated space environment[J]. VACUUM, 2018, 55(5): 66 -70 .
[4] ZHENG Lie, LI Hong. Design of 200kV/2mA continuous adjustable DC high voltage generator[J]. VACUUM, 2018, 55(6): 10 -13 .
[5] CHAI Xiao-tong, WANG Liang, WANG Yong-qing, LIU Ming-kun, LIU Xing-zhou, GAN Shu-yi. Operating parameter data acquisition system for single vacuum pump based on STM32F103 microcomputer[J]. VACUUM, 2018, 55(5): 15 -18 .
[6] SUN Li-zhi, YAN Rong-xin, LI Tian-ye, JIA Rui-jin, LI Zheng, SUN Li-chen, WANG Yong, WANG Jian, . Research on distributing law of Xenon in big accumulation chamber[J]. VACUUM, 2018, 55(5): 38 -41 .
[7] HUANG Si, WANG Xue-qian, MO Yu-shi, ZHANG Zhan-fa, YING Bing. Experimental study on similarity law of liquid ring compressor performances[J]. VACUUM, 2018, 55(5): 42 -45 .
[8] JI Ming, SUN Liang, YANG Min-bo. Design of automatic sealing and locking scheme for lunar sample[J]. VACUUM, 2018, 55(6): 24 -27 .
[9] LI Min-jiu, XIONG Tao, JIANG Ya-lan, HE Yan-bin, CHEN Qing-chuan. 20kV high voltage based on double transistor forward converter pulse power supply for metal deburring[J]. VACUUM, 2018, 55(5): 19 -24 .
[10] LIU Yan-wen, MENG Xian-zhan, TIAN Hong, LI Fen, SHI Wen-qi, ZHU Hong, GU Bing. Test of ultra high vacuum in space traveling-wave tube[J]. VACUUM, 2018, 55(5): 25 -28 .